19. Luxembourg
Total expatriate package cost: $204,396
One of the smallest countries in the world, Luxembourg is used to punching well above its weight, and making the list of the 21 highest-paying countries for expats simply proves this point. If the high-flying, intense pressure life is not for you, Luxembourg will be a heaven, where you have an opportunity to slow down your life, stop and smell the roses, to use a worn-out cliche.